Nanoscale homochiral C(3)-symmetric mixed-valence manganese cluster complexes with both ferromagnetic and ferroelectric properties.
نویسندگان
چکیده
Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of which comprises a 22-nucleus mixed-valence manganese(II/III) supratetrahedral cluster cation and an equilateral-triangle trinuclear manganese(III) cluster anion with C(3) symmetry.
منابع مشابه
Unusual oxidation state distributions observed for two mixed-valence heptanuclear manganese disc-like clusters.
The synthesis, structures and magnetic properties of two new mixed-valence heptanuclear manganese clusters are described. Both complexes utilize triethanolamine (teaH(3)) as a bridging ligand, displaying near planar, disc-like metal topologies and are of formulae [Mn(II)(4)Mn(IV)(3)(tea)(teaH(2))(3)(peolH)(4)](BF(4))(2)·solv (1) and [Mn(II)(4)Mn(III)(3)F(3)(tea)(teaH)(teaH(2))(2)(piv)(4)(Hpiv)(...
متن کاملInvestigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium
We report the syntheses and electrochemical properties of nine new clusters ([LLnMn(IV)3O4(OAc)3(DMF)n](+) (Ln = La(3+), Ce(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), Dy(3+), Yb(3+), and Lu(3+), n = 2 or 3)) supported by a ligand (L(3-)) based on a 1,3,5-triarylbenzene motif appended with alkoxide and pyridine donors. All complexes were obtained by metal substitution of Ca(2+) with lanthanides upon t...
متن کاملTwo mono- and dinuclear Eu(III) enantiomeric pairs based on chiral bis-bidentate bridging ligands: synthesis, structures, luminescent and ferroelectric properties.
Using the enantiomeric bis-bidentate bridging ligands (+)/(-)-2,5-bis(4,5-pinene-2-pyridyl)pyrazine (L(S)/L(R)) and depending on the ratio control of reactants, two mono- and dinuclear Eu(III)-based enantiomeric pairs with the formulae Eu(dbm)(3)L(R/S)·2H(2)O (L(R) in R-1, L(S) in S-1 and dbm = dibenzoylmethanato) and Eu(2)(dbm)(6)L(R/S)·H(2)O (L(R) in R-2 and L(S) in S-2) have been stereoselec...
متن کاملFirst one-dimensional homochiral stairway-like Cu(II) chains: crystal structures, circular dichroism (CD) spectra, ferroelectricity and antiferromagnetic properties.
The reactions of enantiopure chiral ligands (+)/(−)-4,5-pinenepyridyl-2-pyrazine (LS/LR) with CuCl2·2H2O in CH3OH/CH2Cl2 solution led to the formations of one-dimensional homochiral enantiomeric pairs with the formula [Cu(LR/S)Cl2]n·2H2O (R-1 and S-1, the isomers containing the LR and LS ligands, respectively). The circular dichroism (CD) spectra verified their chiroptical activities and enanti...
متن کاملSynthesis of mixed-valence hexanuclear Mn(II/III) clusters from its Mn(II) precursor: variations of catecholase-like activity and magnetic coupling.
One Mn(II) coordination polymer, [Mn(o-(NO2)C6H4COO)2(pyz)(H2O)]n (1), has been synthesized and oxidized with n-Bu4NMnO4 in non-aqueous media to two mixed-valence hexanuclear Mn(II/III) complexes [MnIII2MnII4O2(pyz)0.61/(MeOH)0.39(o-(NO2)C6H4COO)10·(H2O)·{(CH3)2CO}2]·(CH3)2CO (2) and [MnIII2MnII4O2(pyz)0.28/(MeCN)3.72(o-(NO2)C6H4COO)10·(H2O)] (3) (where pyz = pyrazine). All three complexes were...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 12 شماره
صفحات -
تاریخ انتشار 2010